WAEC 2013 Chemistry Questions and Answer

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1. Which of the following instruments is used in detecting the presence of radiation?

  • Cathode ray tube
  • Geiger-Muller counter
  • Mass spectrometer
  • X-ray tube

2. The molecule which has a linear shape is

  • CH4
  • NH3
  • H2S
  • CO2

3. The formula of the compound formed between a trivalent metal, M and a divalent non metal, Y is

  • M2Y2
  • M3Y2
  • MY
  • M3Y

4. An atom of an element X gains two electrons. The symbol of the ion formed is

  • X+
  • X2+
  • X2-
  • X-

5. Which of the following statements is correct?

  • Atomic size decreases down the group
  • Atomic size increases across the period
  • Anions are smaller than the parent atom
  • Cations are smaller than the parent atom

6. Which of the following arrangements represents the correct order of electronic energy level?

  • 2p 2s 3p 3s 3d 4s
  • 2s 2p 3s 3p 3d 4s
  • 2s 2p 3s 3p 4s 3d
  • 2s 3s 2p 3p 4s 3d

7. The element with electron configuration 1s2 2s2 2p6 3s2 3p1 belongs to

  • s-block, period 3, group 1
  • p-block, period 3, group 2
  • s-block, period 3, group 3
  • p-block, period 3, group 3

8. In the periodic table, all the elements within the same group have the same

9. Which of the following halogens is liquid at room temperature?

  • Iodine
  • Chlorine
  • Bromine
  • Fluorine

10. Rare gases are stable because they

  • Chemically active
  • Contain equal number of protons and neutrons
  • Contain more electrons than protons
  • Have octet structures

11. In the periodic table, alkaline earth metals can be found in group

  • I
  • II
  • VI
  • VII

12. In which of the following series are atoms arranged in order of increasing ionization energy?

  • Li, Na, K
  • B, Be, Li
  • Have octet structures
  • Be, Mg, Ca

13. Which of the following types is responsible for high boiling point of water?

  • Metallic bond
  • Covalent bond
  • Ionic bond
  • Hydrogen bond

14. In metallic solid, the forces of attraction is between the mobile valence electrons and the

  • Atoms
  • Neutrons
  • Negative ions
  • Positively charged nuclei

15. The bonds is crystalline ammonium chloride are

  • Covalent and dative
  • Ionic and covalent
  • Ionic, covalent and dative
  • Ionic, covalent and hydrogen bond

16. Which of the following elements is diatomic?

  • Sodium
  • Oxygen
  • Iron
  • Neon

17. Noble gas molecules are held together by

  • Van der Waals forces
  • Hydrogen bonds
  • Dative bonds
  • Covalent bonds

18. Which of the following statement about nuclear reaction is correct? The reaction

  • InvolvesNneutron only
  • Takes place inside the nucleus
  • Is governed by temperature and pressure
  • Involves protons and electrons only

19. Consider the reaction represented by the following equation C2H2+ yH2 C2H6. The value of y in the reaction is

  • 4
  • 3
  • 2
  • 1

20. The volume of 0.25 moldm3 solution of K0H that would yield 6.5grams of solid K0H on evaporation is (K=39.0; O=16.0; H=1.00)

  • 464.30cm3
  • 625.00cm3
  • 1000.00cm3
  • 2153.80cm3

21. The percentage by mass of calcium Ca(OCL)2 Ca = 40.0; Cl = 35.5; O = 16.0

  • 28.0%
  • 31.6%
  • 443.8%
  • 44.5%

22. The gas law which describes the relationship between volume and temperature is .

  • Boyle’s law
  • Charles’ law
  • Dalton’s law
  • Graham’s law

23. Which of the following phenomena leads to decrease volume of a liquid in an open container?

  • Brownian motion
  • Diffusion
  • Evaporation
  • Sublimation

24. The pressure exerted by a gas is a function of the

  • Total volume of the gas
  • Speed of the gaseous molecules
  • Mass of each gaseous molecule
  • Frequency of collision between gaseous molecules

25. Which of the following gases are arranged in increasing order of diffusion rate? H= 1.0; C=12; N = 14.0; O = 16; S = 32

  • SO2, O2, NH3, H2
  • H2S, NH2, O2, SO2
  • CO2, N2O, O2, SO2
  • NH3, NO2, N2, CO2

26. Which of the following variables is a measure of the average kinetic of the molecule of a gas?26. Which of the following variables is a measure of the average kinetic of the molecule of a gas?27. When heat is absorbed during chemical reaction the reaction is aid to be

27. When heat is absorbed during chemical reaction the reaction is aid to be

  • Adiabatic
  • Endothermic
  • Exothermic
  • Isothermal

28. The aqueous solution which has pH > 7 is

  • FeCL3(aq)
  • CuSO4(aq)
  • KNO3 (aq)
  • Na2CO3(aq)

29. Which of the following acids would readily react with CaCO3 to liberate CO2?

  • CH3COOH
  • H2SO4
  • H2SO3
  • HNO3

30. Which of the following compounds crystallizes without water of crystallization?

  • MgSO4
  • Na2CO3
  • NaCl
  • FeSO4

31. A substance is said to be impure if

  • its melting point range is wide
  • it dissolves in water with difficulty
  • it has a low melting point
  • it is coloured

32. The following factors affect the solubility of a solid in a given solvent except

  • Nature of solute
  • Nature of solvent
  • Pressure
  • Temperature

33. Consider the reaction represented by the equation N2O4(g) 2NO2(aq) ; ∆ = + x K Jmol-1.what happen when the temperature is reduced at equilibrium?

  • Concentration of N2O 4 (g)decreases
  • Concentration of N2O4(g) increases
  • Pressure exerted by the gases increases
  • pressure exerted by the gases remains constant

34. Which of the following cells produce electrical energy from chemical reactions?I Lead – acid battery II dry cell III Daniel cell IV Electrolytic cell

  • I and II
  • I,II and III
  • II,III and IV
  • I,III and IV only

35. What happens at the cathode during electrolysis?

  • Anion is oxidized
  • Anion loses electrons
  • Cation is oxidized
  • Cation is discharge

36. Which of the following substance are electrolytes? I PbBr₂₍ᵢ₎ II NaCL₍aq₎ III NaCl(s) IV C6H12O6(aq)

  • I and II only
  • I,II and IV
  • II, III and IV only
  • I, III, and IV only

37. Consider the redox reaction as represented by the following equation: I2 (aq) + 2S2O32- (aq) 2I-(aq) + S4O62-(aq) which of the species is reduced?

  • S4O62- (aq)
  • S4O32- (aq)
  • I2 (aq)
  • I2-(aq)

38. The separation of petroleum fraction depends on the differences in their

  • Melting point
  • Molar masses
  • solubilities
  • Boiling points

39. 39. The major point formed by the reaction between ethanoic acid and aqueous sodium hydroxide is

  • Soap
  • Sodium ethanoate
  • Sodium methoxide
  • Water

40. Which of the following organic compounds would decolourise bromine water?

  • Benzene
  • Cyclobutane
  • Hexane
  • Penane

41. 41. How many isomers are in C3H6Cl2?

  • 2
  • 3
  • 4
  • 5

42. A colourless hydrocarbon with a sweet smell undergoes substitution reaction. The hydrocarbon is likely to be

  • alkanol
  • benzene
  • ester
  • methane

43. Which of the follwoing reactions is common to all hydrocarbons

  • combustion
  • addition
  • polymerization
  • condensation

44. A hydrocarbon compound contains 92.3% carbon. Determine its empirical formular
[H:1, C:12]

  • CH
  • CH2
  • CH3
  • C2H3

45. The main function of limestone in a blast furnace is to

  • act as catalyst
  • act as reducing agent
  • remove impurity
  • supply carbon(iv)oxide

46. Which of the following raw materials is used in plastic industry?

  • ethene
  • methane
  • calcium
  • hydrogen

47. Which of the following statements about thermoplastic material is correct? They

  • do not melt on heating
  • harden on heating
  • decompose on heating
  • soften and melt on heating

48. Bronze is a mixture of

  • Cu and Mg
  • Cu and Sn
  • Cu and Zn
  • Cu and Pb

49. WHich of the following statements about fine chemical is correct?

  • It is injurious to the health
  • has low degree of purity
  • is produced in relatively small amount
  • can be stored for a long time

50. Which of the following materials is classified as a non-biodegradable pollutant?

  • Animal hide
  • Paper
  • Plastic
  • Wood

ANSWERS

  1. B
  2. D
  3. A
  4. C
  5. D
  6. C
  7. D
  8. B
  9. C
  10. D
  11. B
  12. C
  13. D
  14. C
  15. B
  16. A
  17. B
  18. B
  19. A
  20. A
  21. B
  22. C
  23. D
  24. A
  25. C
  26. B
  27. D
  28. B
  29. C
  30. A
  31. C
  32. B
  33. D
  34. A
  35. B
  36. D
  37. B
  38. A
  39. A
  40. C
  41. A
  42. A
  43. D
  44. A
  45. D
  46. B
  47. C
  48. C